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Issue 33, 2014
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Synthesis of a tetrabenzotriazacorrole μ-oxo dimer and investigation of its stacking effect

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Abstract

A μ-oxo dimer of phosphorus(V) tetrabenzotriazacorrole (PTBC) has been synthesized and characterized for the first time. Spectroscopic and theoretical analysis support the opinion that two PTBC chromophore groups interact with each other, while the low-symmetric PTBC structure is also efficient for generating singlet oxygen.

Graphical abstract: Synthesis of a tetrabenzotriazacorrole μ-oxo dimer and investigation of its stacking effect

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Supplementary files

Article information


Submitted
12 Feb 2014
Accepted
25 Feb 2014
First published
26 Feb 2014

Chem. Commun., 2014,50, 4312-4314
Article type
Communication
Author version available

Synthesis of a tetrabenzotriazacorrole μ-oxo dimer and investigation of its stacking effect

T. Furuyama, Y. Sugiya and N. Kobayashi, Chem. Commun., 2014, 50, 4312
DOI: 10.1039/C4CC01115E

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