Issue 33, 2014
From the journal:

Chemical Communications

Synthesis of a tetrabenzotriazacorrole μ-oxo dimer and investigation of its stacking effect†

Taniyuki Furuyama,a   Yusuke Sugiyaa  and  Nagao Kobayashi*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan
E-mail: nagaok@m.tohoku.ac.jp
Tel: +81 22 795 7719

Abstract

A μ-oxo dimer of phosphorus(V) tetrabenzotriazacorrole (PTBC) has been synthesized and characterized for the first time. Spectroscopic and theoretical analysis support the opinion that two PTBC chromophore groups interact with each other, while the low-symmetric PTBC structure is also efficient for generating singlet oxygen.

Graphical abstract: Synthesis of a tetrabenzotriazacorrole μ-oxo dimer and investigation of its stacking effect

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Article information

DOI
https://doi.org/10.1039/C4CC01115E
Article type
Communication
Submitted
12 Feb 2014
Accepted
25 Feb 2014
First published
26 Feb 2014

Chem. Commun., 2014,50, 4312-4314

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Synthesis of a tetrabenzotriazacorrole μ-oxo dimer and investigation of its stacking effect

T. Furuyama, Y. Sugiya and N. Kobayashi, Chem. Commun., 2014, 50, 4312 DOI: 10.1039/C4CC01115E

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