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Issue 28, 2014
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Expeditious synthesis of 1-aminoindane derivatives achieved by [1,4]-hydride shift mediated C(sp3)–H bond functionalization

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Abstract

Described herein is a [1,4]-hydride shift mediated expeditious synthesis of 1-aminoindane derivatives. A wide variety of substrates could be employed in this reaction to afford various indane derivatives in good to excellent chemical yields. Examination of the amine moiety revealed that the sterically hindered amine is the key to achieving both low catalyst loading and excellent chemical yields.

Graphical abstract: Expeditious synthesis of 1-aminoindane derivatives achieved by [1,4]-hydride shift mediated C(sp3)–H bond functionalization

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Article information


Submitted
03 Feb 2014
Accepted
13 Feb 2014
First published
14 Feb 2014

Chem. Commun., 2014,50, 3729-3731
Article type
Communication

Expeditious synthesis of 1-aminoindane derivatives achieved by [1,4]-hydride shift mediated C(sp3)–H bond functionalization

K. Mori, K. Kurihara and T. Akiyama, Chem. Commun., 2014, 50, 3729
DOI: 10.1039/C4CC00894D

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