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Issue 38, 2014
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Highly active phosphite gold(I) catalysts for intramolecular hydroalkoxylation, enyne cyclization and furanyne cyclization

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Abstract

New and highly active mononuclear phosphite gold(I) catalysts are described. Turn-over numbers up to 37 000 for the furan–yne reaction and up to 28 000 000 for the two-fold hydroalkoxylation of alkynes are reported.

Graphical abstract: Highly active phosphite gold(i) catalysts for intramolecular hydroalkoxylation, enyne cyclization and furanyne cyclization

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Publication details

The article was received on 30 Jan 2014, accepted on 27 Mar 2014 and first published on 27 Mar 2014


Article type: Communication
DOI: 10.1039/C4CC00839A
Chem. Commun., 2014,50, 4937-4940

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    Highly active phosphite gold(I) catalysts for intramolecular hydroalkoxylation, enyne cyclization and furanyne cyclization

    M. C. Blanco Jaimes, F. Rominger, M. M. Pereira, R. M. B. Carrilho, S. A. C. Carabineiro and A. S. K. Hashmi, Chem. Commun., 2014, 50, 4937
    DOI: 10.1039/C4CC00839A

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