Issue 37, 2014
From the journal:

Chemical Communications

Novel binding regioselectivity in the interpenetration of a non-symmetric axle into a non-symmetric pillar[5]arene wheel†

Xiaoyan Shu,ab   Wei Chen,b   Dabin Hou,*a   Qingbin Meng,*c   Renlin Zhenga  and  Chunju Li*b  

* Corresponding authors

a School of Life Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, Sichuan, P. R. China
E-mail: dbhou@126.com

b Department of Chemistry, Shanghai University, Shanghai, P. R. China
E-mail: cjli@shu.edu.cn

c Beijing Institute of Pharmacology and Toxicology, Beijing, P. R. China
E-mail: nankaimqb@sina.com

Abstract

We describe the regioselective complexation of a non-symmetric 5-bromovaleronitrile axle by a non-symmetric pillar[5]arene bearing different alkyl (methyl and pentyl) rims, forming an oriented interpenetrated complex with the directionality of CN@methyl rim and Br@pentyl rim.

Graphical abstract: Novel binding regioselectivity in the interpenetration of a non-symmetric axle into a non-symmetric pillar[5]arene wheel

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Article information

DOI
https://doi.org/10.1039/C4CC00800F
Article type
Communication
Submitted
29 Jan 2014
Accepted
27 Feb 2014
First published
27 Feb 2014

Chem. Commun., 2014,50, 4820-4823

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Novel binding regioselectivity in the interpenetration of a non-symmetric axle into a non-symmetric pillar[5]arene wheel

X. Shu, W. Chen, D. Hou, Q. Meng, R. Zheng and C. Li, Chem. Commun., 2014, 50, 4820 DOI: 10.1039/C4CC00800F

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