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Issue 47, 2014
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Efficient syntheses of pillar[6]arene-based hetero[4]rotaxanes using a cooperative capture strategy

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Abstract

While a single pillar[6]arene ring, nestling between two cucurbit[6]uril rings in a series of three hetero[4]rotaxanes, is conformationally mobile in solution, it adopts the energetically most favourable conformation with local C3V symmetry in the solid state.

Graphical abstract: Efficient syntheses of pillar[6]arene-based hetero[4]rotaxanes using a cooperative capture strategy

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Publication details

The article was received on 27 Jan 2014, accepted on 25 Feb 2014 and first published on 04 Mar 2014


Article type: Communication
DOI: 10.1039/C4CC00733F
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Citation: Chem. Commun., 2014,50, 6196-6199
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    Efficient syntheses of pillar[6]arene-based hetero[4]rotaxanes using a cooperative capture strategy

    X. Hou, C. Ke, C. Cheng, N. Song, A. K. Blackburn, A. A. Sarjeant, Y. Y. Botros, Y. Yang and J. F. Stoddart, Chem. Commun., 2014, 50, 6196
    DOI: 10.1039/C4CC00733F

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