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Issue 47, 2014
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Efficient syntheses of pillar[6]arene-based hetero[4]rotaxanes using a cooperative capture strategy

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Abstract

While a single pillar[6]arene ring, nestling between two cucurbit[6]uril rings in a series of three hetero[4]rotaxanes, is conformationally mobile in solution, it adopts the energetically most favourable conformation with local C3V symmetry in the solid state.

Graphical abstract: Efficient syntheses of pillar[6]arene-based hetero[4]rotaxanes using a cooperative capture strategy

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Supplementary files

Article information


Submitted
27 Jan 2014
Accepted
25 Feb 2014
First published
04 Mar 2014

Chem. Commun., 2014,50, 6196-6199
Article type
Communication
Author version available

Efficient syntheses of pillar[6]arene-based hetero[4]rotaxanes using a cooperative capture strategy

X. Hou, C. Ke, C. Cheng, N. Song, A. K. Blackburn, A. A. Sarjeant, Y. Y. Botros, Y. Yang and J. F. Stoddart, Chem. Commun., 2014, 50, 6196
DOI: 10.1039/C4CC00733F

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