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Abstract | Cited by

In this work, we have disclosed the nickel-catalyzed unactivated β-C(sp3)–H bond arylation of aliphatic acid derivatives with aryl iodides/bromides via bidentate chelation-assistance of an 8-aminoquinoline moiety. These preliminary results indicate the intrinsic catalytic potential of nickel metal for unactivated C(sp3)–H bond arylation.

Graphical abstract: Nickel-catalyzed chelation-assisted direct arylation of unactivated C(sp3)–H bonds with aryl halides

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