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Issue 26, 2014
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Springloaded porphyrin NHC hybrid rhodium(iii) complexes: carbene dissociation and oxidation catalysis

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Abstract

Porphyrin rhodium(III) complexes accommodate one or two NHC ligands in the apical position, which leads to severe porphyrin distortion and dearomatization. The strain in the bis(carbene) complex induces facile carbene dissociation and the formation of a catalytically active site for alcohol oxidation.

Graphical abstract: Springloaded porphyrin NHC hybrid rhodium(iii) complexes: carbene dissociation and oxidation catalysis

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Supplementary files

Article information


Submitted
20 Jan 2014
Accepted
05 Feb 2014
First published
06 Feb 2014

Chem. Commun., 2014,50, 3488-3490
Article type
Communication

Springloaded porphyrin NHC hybrid rhodium(III) complexes: carbene dissociation and oxidation catalysis

J. Olguín, H. Müller-Bunz and M. Albrecht, Chem. Commun., 2014, 50, 3488
DOI: 10.1039/C4CC00497C

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