Issue 44, 2014

P-chiral phosphorus heterocycles: a straightforward synthesis

Abstract

A straightforward synthesis of P-chiral polycyclic 7-phospha-norbornenes via an asymmetric Diels–Alder reaction is presented. The employed starting materials are cheap, easily accessible and of structural diversity facilitating a new flexible route towards differently functionalised P-chiral phosphanes.

Graphical abstract: P-chiral phosphorus heterocycles: a straightforward synthesis

Supplementary files

Article information

Article type
Communication
Submitted
14 Jan 2014
Accepted
16 Mar 2014
First published
17 Mar 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 5826-5828

Author version available

P-chiral phosphorus heterocycles: a straightforward synthesis

T. Möller, P. Wonneberger, N. Kretzschmar and E. Hey-Hawkins, Chem. Commun., 2014, 50, 5826 DOI: 10.1039/C4CC00318G

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