Issue 26, 2014
From the journal:

Chemical Communications

A new metal–organic framework with ultra-high surface area†

Ronny Grünker,a   Volodymyr Bon,a   Philipp Müller,a   Ulrich Stoeck,a   Simon Krause,a   Uwe Mueller,b   Irena Senkovskaa  and  Stefan Kaskel*a  

* Corresponding authors

a Department of Inorganic Chemistry, Technische Universität Dresden, Bergstrasse 66, D-01069 Dresden, Germany
E-mail: stefan.kaskel@chemie.tu-dresden.de

b Helmholtz-Zentrum Berlin für Materialien und Energie, BESSY-MX Group, Albert-Einstein-Strasse 15, D-12489 Berlin, Germany

Abstract

A new mesoporous MOF, Zn4O(bpdc)(btctb)4/3 (DUT-32), containing linear ditopic (bpdc2−; 4,4′-biphenylenedicarboxylic acid) and tritopic (btctb3−; 4,4′,4′′-[benzene-1,3,5-triyltris(carbonylimino)]tris-benzoate) linkers, was synthesised. The highly porous solid has a total pore volume of 3.16 cm3 g−1 and a specific BET surface area of 6411 m2 g−1, adding this compound to the top ten porous materials with the highest BET surface area.

Graphical abstract: A new metal–organic framework with ultra-high surface area

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Article information

DOI
https://doi.org/10.1039/C4CC00113C
Article type
Communication
Submitted
06 Jan 2014
Accepted
04 Feb 2014
First published
04 Feb 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 3450-3452

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A new metal–organic framework with ultra-high surface area

R. Grünker, V. Bon, P. Müller, U. Stoeck, S. Krause, U. Mueller, I. Senkovska and S. Kaskel, Chem. Commun., 2014, 50, 3450 DOI: 10.1039/C4CC00113C

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