Tungsten nanoparticles were obtained from liquid-ammonia-based synthesis via reduction of WCl6 with dissolved sodium. The W0 nanoparticles exhibit a diameter of 1–2 nm and can be dispersed in alkanes, showing a grayish-orange color due to red-shifted plasmon resonance absorption.
C. Schöttle, P. Bockstaller, D. Gerthsen and C. Feldmann, Chem. Commun., 2014, 50, 4547 DOI: 10.1039/C3CC49854A
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