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Issue 22, 2014
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Rational design of sulfoxide–phosphine ligands for Pd-catalyzed enantioselective allylic alkylation reactions

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Abstract

A new type of chiral sulfoxide–phosphine ligands have been developed by a rational combination of two privileged scaffolds for Pd-catalyzed asymmetric allylic alkylation reactions. Under optimized conditions, generally high yields (up to 97%) and excellent enantioselectivities (up to >99% ee) were obtained.

Graphical abstract: Rational design of sulfoxide–phosphine ligands for Pd-catalyzed enantioselective allylic alkylation reactions

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Article information


Submitted
14 Dec 2013
Accepted
24 Jan 2014
First published
27 Jan 2014

Chem. Commun., 2014,50, 2873-2875
Article type
Communication
Author version available

Rational design of sulfoxide–phosphine ligands for Pd-catalyzed enantioselective allylic alkylation reactions

H. Cheng, B. Feng, L. Chen, W. Guo, X. Yu, L. Lu, J. Chen and W. Xiao, Chem. Commun., 2014, 50, 2873
DOI: 10.1039/C3CC49488H

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