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Issue 54, 2014
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A single chain magnet involving hexacyanoosmate

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Abstract

The first single chain magnet (SCM) based on orbitally degenerate hexacyanoosmate(III) was prepared. The high values of energy barriers for the [Mn(acacen)Os(CN)6]2− complex of 81 and 48.4 K are the result of interplay of three axes anisotropic coupling of [Os(CN)6]3− with zero field splitted Mn3+.

Graphical abstract: A single chain magnet involving hexacyanoosmate

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Article information


Submitted
25 Nov 2013
Accepted
12 May 2014
First published
12 May 2014

Chem. Commun., 2014,50, 7150-7153
Article type
Communication
Author version available

A single chain magnet involving hexacyanoosmate

E. V. Peresypkina, A. M. Majcher, M. Rams and K. E. Vostrikova, Chem. Commun., 2014, 50, 7150
DOI: 10.1039/C3CC48972H

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