Issue 29, 2014
From the journal:

Chemical Communications

Highly enantioselective hydroamination to six-membered rings by heterobimetallic catalysts†

Lenard Hussein,*a   Nibadita Purkait,a   Mustafa Biyikal,a   Eugenia Tausch,b   Peter W. Roeskyb  and  Siegfried Blechert*a  

* Corresponding authors

a Institut für Chemie, Technische Universität Berlin, Straße des 17. Juni 135, 10623 Berlin, Germany
E-mail: blechert@chem.tu-berlin.de

b Institut für Anorganische Chemie, Karlsruher Institut für Technologie (KIT), Engesserstr. 15, Geb. 30.45, 76131 Karlsruhe, Germany

Abstract

New bimetallic Zn/Zr salen-type systems were employed as catalysts in the asymmetric intramolecular hydroamination reaction. High enantioselectivity for the formation of piperidines of up to 98% ee were observed.

Graphical abstract: Highly enantioselective hydroamination to six-membered rings by heterobimetallic catalysts

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC48874H
Article type
Communication
Submitted
20 Nov 2013
Accepted
19 Feb 2014
First published
04 Mar 2014

Chem. Commun., 2014,50, 3862-3864

Permissions

Request permissions

Highly enantioselective hydroamination to six-membered rings by heterobimetallic catalysts

L. Hussein, N. Purkait, M. Biyikal, E. Tausch, P. W. Roesky and S. Blechert, Chem. Commun., 2014, 50, 3862 DOI: 10.1039/C3CC48874H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements