Issue 29, 2014

Highly enantioselective hydroamination to six-membered rings by heterobimetallic catalysts

Abstract

New bimetallic Zn/Zr salen-type systems were employed as catalysts in the asymmetric intramolecular hydroamination reaction. High enantioselectivity for the formation of piperidines of up to 98% ee were observed.

Graphical abstract: Highly enantioselective hydroamination to six-membered rings by heterobimetallic catalysts

Supplementary files

Article information

Article type
Communication
Submitted
20 Nov 2013
Accepted
19 Feb 2014
First published
04 Mar 2014

Chem. Commun., 2014,50, 3862-3864

Highly enantioselective hydroamination to six-membered rings by heterobimetallic catalysts

L. Hussein, N. Purkait, M. Biyikal, E. Tausch, P. W. Roesky and S. Blechert, Chem. Commun., 2014, 50, 3862 DOI: 10.1039/C3CC48874H

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