Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 27th March 2019 from 11:00 AM to 1:00 PM (GMT).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 11, 2014
Previous Article Next Article

Hydrogen activation with perfluorinated organoboranes: 1,2,3-tris(pentafluorophenyl)-4,5,6,7-tetrafluoro-1-boraindene

Author affiliations

Abstract

The perfluorinated boraindene 3 was synthesized and fully characterized. Both computational and crystallographic data show that 3 is antiaromatic. Compound 3 was shown to react reversibly with H2 and to catalyse the hydrogenation of cyclohexene. The mechanism of catalysis was probed experimentally and computationally.

Graphical abstract: Hydrogen activation with perfluorinated organoboranes: 1,2,3-tris(pentafluorophenyl)-4,5,6,7-tetrafluoro-1-boraindene

Back to tab navigation

Supplementary files

Publication details

The article was received on 18 Nov 2013, accepted on 08 Dec 2013 and first published on 09 Dec 2013


Article type: Communication
DOI: 10.1039/C3CC48796B
Author version
available:
Download author version (PDF)
Citation: Chem. Commun., 2014,50, 1295-1298

  •   Request permissions

    Hydrogen activation with perfluorinated organoboranes: 1,2,3-tris(pentafluorophenyl)-4,5,6,7-tetrafluoro-1-boraindene

    A. Y. Houghton, V. A. Karttunen, W. E. Piers and H. M. Tuononen, Chem. Commun., 2014, 50, 1295
    DOI: 10.1039/C3CC48796B

Search articles by author

Spotlight

Advertisements