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Issue 14, 2014

Palladium[ii] catalysed C(sp3)–H oxidation of dimethyl carbamoyl tetrahydrocarbazoles

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Abstract

Dimethyl carbamoyl tetrahydrocarbazoles undergo directed oxidation using standard conditions to exclusively provide products from C(sp3)–H oxidation. This result is in contrast to recent studies on the directed C–H olefination of hydrocarbazoles, which result in selective aromatic functionalisation.

Graphical abstract: Palladium[ii] catalysed C(sp3)–H oxidation of dimethyl carbamoyl tetrahydrocarbazoles

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Article information


Submitted
08 Nov 2013
Accepted
04 Dec 2013
First published
04 Dec 2013

Chem. Commun., 2014,50, 1757-1760
Article type
Communication

Palladium[II] catalysed C(sp3)–H oxidation of dimethyl carbamoyl tetrahydrocarbazoles

Y. Nakano and D. W. Lupton, Chem. Commun., 2014, 50, 1757 DOI: 10.1039/C3CC48545E

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