Issue 15, 2014
From the journal:

Chemical Communications

Nitronyl nitroxide–metal complexes as metallo-ligands for the construction of hetero-tri-spin (2p–3d–4f) chains†

Mei Zhu,a   Xuelan Mei,a   Yue Ma,a   Licun Li,*a   Daizheng Liaoa  and  Jean-Pascal Sutter*bc  

* Corresponding authors

a Department of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry and Tianjin Key Laboratory of Metal and Molecule-based Material Chemistry, Nankai University, Tianjin 300071, China
E-mail: llicun@nankai.edu.cn

b CNRS, LCC (Laboratoire de Chimie de Coordination), 205, Route de Narbonne, F-31077 Toulouse, France
E-mail: sutter@lcc-toulouse.fr

c Université de Toulouse, UPS, INPT, LCC, F-31077 Toulouse, France

Abstract

A novel approach for the preparation of hetero-tri-spin magnetic compounds is described. It consists in using preformed metal–nitronyl nitroxide complexes as metallo-ligands in an assembling process involving an additional metal centre. This is illustrated by two unprecedented radical–Cu–Ln chain compounds (Ln = Gd3+, Tb3+).

Graphical abstract: Nitronyl nitroxide–metal complexes as metallo-ligands for the construction of hetero-tri-spin (2p–3d–4f) chains

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC48110G
Article type
Communication
Submitted
22 Oct 2013
Accepted
03 Dec 2013
First published
09 Jan 2014

Chem. Commun., 2014,50, 1906-1908

Permissions

Request permissions

Nitronyl nitroxide–metal complexes as metallo-ligands for the construction of hetero-tri-spin (2p–3d–4f) chains

M. Zhu, X. Mei, Y. Ma, L. Li, D. Liao and J. Sutter, Chem. Commun., 2014, 50, 1906 DOI: 10.1039/C3CC48110G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements