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We report the formation of luminescent silver clusters in zeolites by a fast, highly accurate, and controlled activation of silver ions entrapped in sodalite cages of LTA and FAU zeolites using high-brilliance soft X-rays. The activated luminescent samples were investigated by employing a combination of stationary and time-resolved spectroscopic techniques.

Graphical abstract: X-ray irradiation-induced formation of luminescent silver clusters in nanoporous matrices

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