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Abstract | Cited by

The first metal-free reduction of lignin model compounds is described. Using inexpensive Et3SiH, PMHS and TMDS hydrosilanes as reductants, α-O-4 and β-O-4 linkages are reduced to primary alcohols and phenols under mild conditions using B(C6F5)3 as an efficient catalyst.

Graphical abstract: Unprecedented organocatalytic reduction of lignin model compounds to phenols and primary alcohols using hydrosilanes

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