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Issue 4, 2014
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Synthesis and properties of a Cu(ii) complexing pyrazole ligandoside in DNA

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Abstract

The development of metal base pairs is of immense importance for the construction of DNA nanostructures. Here we report the synthesis of a biaryl pyrazole–phenol nucleoside that forms in DNA a stable self-pair upon complexation of a Cu(II) ion. A sequence with five consecutive pyrazole nucleotides allows the complexation of five Cu(II) ions in a row.

Graphical abstract: Synthesis and properties of a Cu(ii) complexing pyrazole ligandoside in DNA

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Supplementary files

Article information


Submitted
02 Oct 2013
Accepted
01 Nov 2013
First published
01 Nov 2013

Chem. Commun., 2014,50, 409-411
Article type
Communication

Synthesis and properties of a Cu(II) complexing pyrazole ligandoside in DNA

M. Su, M. Tomás-Gamasa, S. Serdjukow, P. Mayer and T. Carell, Chem. Commun., 2014, 50, 409
DOI: 10.1039/C3CC47561A

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