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Issue 1, 2014
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A novel, rigid diphosphine with an active NHC spacer; di- and trinuclear complexes of d10 coinage metals

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Abstract

A novel N,N′-diphosphanyl-imidazol-2-ylidene acts as a stable, hybrid PCNHCP ligand for M2 or linear M3 (M = Cu, Ag, Au) arrays with metallophilic interactions.

Graphical abstract: A novel, rigid diphosphine with an active NHC spacer; di- and trinuclear complexes of d10 coinage metals

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Article information


Submitted
26 Sep 2013
Accepted
22 Oct 2013
First published
24 Oct 2013

Chem. Commun., 2014,50, 103-105
Article type
Communication

A novel, rigid diphosphine with an active NHC spacer; di- and trinuclear complexes of d10 coinage metals

P. Ai, A. A. Danopoulos, P. Braunstein and K. Yu. Monakhov, Chem. Commun., 2014, 50, 103
DOI: 10.1039/C3CC47370H

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