Supramolecular chains of high nuclearity {MnIII25} barrel-like single molecule magnets

Dimosthenis P. Giannopoulos; Annaliese Thuijs; Wolfgang Wernsdorfer; Melanie Pilkington; George Christou; Theocharis C. Stamatatos

doi:10.1039/C3CC47094F

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Supramolecular chains of high nuclearity {Mn^III₂₅} barrel-like single molecule magnets†

Dimosthenis P. Giannopoulos,^a Annaliese Thuijs,^b Wolfgang Wernsdorfer,^c Melanie Pilkington,^a George Christou^b and Theocharis C. Stamatatos*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Brock University, St. Catharines, Ontario, Canada
E-mail: tstamatatos@brocku.ca
Tel: +1-905-688-5550 Ext. 3400

^b Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, USA

^c Institut Néel, CNRS, Nanoscience Department, BP 166, 380412 Grenoble Cedex 9, France

Abstract

The first application of 1-methyl-1H-pyrrole-2-carbaldehyde oxime as a ligand for the coordination of paramagnetic transition metal ions has afforded a new {Mn^III₂₅} barrel-like cluster linked via Na⁺ cations into a 1D polymeric topology that exhibits single-molecule magnetic behaviour.

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Article information

DOI: https://doi.org/10.1039/C3CC47094F
Article type: Communication
Submitted: 16 Sep 2013
Accepted: 30 Oct 2013
First published: 31 Oct 2013

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Chem. Commun., 2014,50, 779-781

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Supramolecular chains of high nuclearity {Mn^III₂₅} barrel-like single molecule magnets

D. P. Giannopoulos, A. Thuijs, W. Wernsdorfer, M. Pilkington, G. Christou and T. C. Stamatatos, Chem. Commun., 2014, 50, 779 DOI: 10.1039/C3CC47094F

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Chemical Communications