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Issue 7, 2014
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Supramolecular chains of high nuclearity {MnIII25} barrel-like single molecule magnets

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Abstract

The first application of 1-methyl-1H-pyrrole-2-carbaldehyde oxime as a ligand for the coordination of paramagnetic transition metal ions has afforded a new {MnIII25} barrel-like cluster linked via Na+ cations into a 1D polymeric topology that exhibits single-molecule magnetic behaviour.

Graphical abstract: Supramolecular chains of high nuclearity {MnIII25} barrel-like single molecule magnets

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Article information


Submitted
16 Sep 2013
Accepted
30 Oct 2013
First published
31 Oct 2013

Chem. Commun., 2014,50, 779-781
Article type
Communication

Supramolecular chains of high nuclearity {MnIII25} barrel-like single molecule magnets

D. P. Giannopoulos, A. Thuijs, W. Wernsdorfer, M. Pilkington, G. Christou and T. C. Stamatatos, Chem. Commun., 2014, 50, 779
DOI: 10.1039/C3CC47094F

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