The reactivity of a number of IrI complexes towards CO2 is explored using [Ir(NHC)(OH)] as a key synthon. CO2 insertion into Ir–O and Ir–N bonds proved facile, yielding a number of IrI-carbonates and -carbamates. Most importantly, reaction between CO2 and IrI–OH led to isolation of the novel [{IrI}2-(μ-κ1:κ2-CO3)] complex.
B. J. Truscott, D. J. Nelson, A. M. Z. Slawin and S. P. Nolan, Chem. Commun., 2014, 50, 286 DOI: 10.1039/C3CC46922K
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