Issue 1, 2014
From the journal:

Chemical Communications

Lewis base-catalyzed reactions of cyclopropenones: novel synthesis of mono- or multi-substituted allenic esters†

Yuan-Liang Yang,a   Zhen Zhang,a   Xiao-Nan Zhang,a   De Wang,a   Yin Wei*a  and  Min Shi*a  

* Corresponding authors

a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, P. R. China
E-mail: weiyin@sioc.ac.cn, mshi@sioc.ac.cn
Fax: +86-21-64166128

Abstract

The reactions of cyclopropenones with nucleophiles (H2O or methanol) could be catalyzed by nitrogen-containing Lewis bases or phosphorus-containing Lewis bases, affording the corresponding mono- or multi-substituted allenic esters in moderate to excellent yields.

Graphical abstract: Lewis base-catalyzed reactions of cyclopropenones: novel synthesis of mono- or multi-substituted allenic esters

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Article information

DOI
https://doi.org/10.1039/C3CC46470A
Article type
Communication
Submitted
24 Aug 2013
Accepted
24 Oct 2013
First published
25 Oct 2013

Chem. Commun., 2014,50, 115-117

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Lewis base-catalyzed reactions of cyclopropenones: novel synthesis of mono- or multi-substituted allenic esters

Y. Yang, Z. Zhang, X. Zhang, D. Wang, Y. Wei and M. Shi, Chem. Commun., 2014, 50, 115 DOI: 10.1039/C3CC46470A

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