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Issue 2, 2014
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A new metal–organic hybrid material with intrinsic resistance-based bistability: monitoring in situ room temperature switching behavior

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Abstract

Two new silver containing materials with TCNQ derivatives were prepared by electrocrystallization. Synchrotron radiation diffraction studies were conducted to determine the structures of the new phases which exhibit unprecedented high room temperature conductivity. The IV characteristics reveal a room-temperature switching behaviour and memory effect based on intrinsic negative differential resistance (NDR). EPR spectroscopic measurements performed under an applied electric field indicate a g-tensor shift that is correlated to the amplitude of current.

Graphical abstract: A new metal–organic hybrid material with intrinsic resistance-based bistability: monitoring in situ room temperature switching behavior

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Article information


Submitted
12 Aug 2013
Accepted
11 Nov 2013
First published
28 Nov 2013

J. Mater. Chem. C, 2014,2, 399-404
Article type
Paper

A new metal–organic hybrid material with intrinsic resistance-based bistability: monitoring in situ room temperature switching behavior

Z. Zhang, H. Zhao, M. M. Matsushita, K. Awaga and K. R. Dunbar, J. Mater. Chem. C, 2014, 2, 399
DOI: 10.1039/C3TC31577K

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