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Issue 31, 2014
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The role of emissive charge transfer states in two polymer–fullerene organic photovoltaic blends: tuning charge photogeneration through the use of processing additives

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Abstract

The role of charge transfer (CT) states in organic photovoltaic systems has been debated in the recent literature. In this paper the device performances of two structurally analogous polymers PDTSiTTz (also known as KP115) and PCPDTTTz blended with PCBM are investigated, focusing on the effect the processing additive diiodooctane (DIO) has on morphology, charge photogeneration, and, in particular, the CT state characteristics. While DIO has a considerable beneficial effect for PCPDTTTz:PCBM photovoltaic devices, negligible effects are observed for PDTSiTTz:PCBM devices. An emissive CT state able to be quenched by DIO was observed for PCPDTTTz:PCBM, despite relatively small morphological changes. This is only the second instance of CT state quenching by a processing additive to be reported. Formation of an emissive CT state is therefore a loss pathway for PCPDTTTz:PCBM, which can be alleviated through the use of DIO to increase the proportion of CT states that dissociate into free charges. Conversely, the CT state of PDTSiTTZ:PCBM is weak and short-lived, with the DIO having little effect. The CT state dissociates more efficiently for this higher crystallinity system, leading to less evidence of emissive CT state recombination, and high charge photogeneration yields and device efficiencies.

Graphical abstract: The role of emissive charge transfer states in two polymer–fullerene organic photovoltaic blends: tuning charge photogeneration through the use of processing additives

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Article information


Submitted
05 May 2014
Accepted
13 Jun 2014
First published
16 Jun 2014

J. Mater. Chem. A, 2014,2, 12583-12593
Article type
Paper
Author version available

The role of emissive charge transfer states in two polymer–fullerene organic photovoltaic blends: tuning charge photogeneration through the use of processing additives

T. M. Clarke, J. Peet, C. Lungenschmied, N. Drolet, X. Lu, B. M. Ocko, A. J. Mozer and M. A. Loi, J. Mater. Chem. A, 2014, 2, 12583
DOI: 10.1039/C4TA02244K

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