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Issue 30, 2014
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Piperidinium tethered nanoparticle-hybrid electrolyte for lithium metal batteries

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Abstract

We report on the synthesis of novel piperidinium-based ionic liquid tethered nanoparticle hybrid electrolytes and investigate their physical and electrochemical properties. Hybrid electrolytes based on the ionic liquid 1-methyl-1-propylpiperidinium bis(trifluoromethanesulfone) imide covalently tethered to silica nanoparticles (SiO2–PP–TFSI) were blended with propylene carbonate–1 M lithium bis(trifluoromethanesulfone) imide (LiTFSI). We employed NMR analysis to confirm the successful creation of the hybrid material. Dielectric and rheological measurements show that these electrolytes exhibit exceptional room-temperature DC ionic conductivity (10−2 to 10−3 S cm−1) as well as high shear mechanical moduli (105 to 106 Pa). Lithium transference numbers were found to increase with particle loading and to reach values as high as 0.22 at high particle loadings where the particle jam to form a soft glassy elastic medium. Analysis of lithium electrodeposits obtained in the hybrid electrolytes using SEM and EDX spectra show that the SiO2–PP–TFSI nanoparticles are able to smooth lithium deposition and inhibit lithium dendrite proliferation in Li metal batteries. LTO|SiO2–PP–TFSI/PC in 1 M LiTFSI|Li half-cells based on the SiO2–PP–TFSI hybrid electrolytes exhibit attractive voltage profiles and trouble-free extended cycling behavior over more than 1000 cycles of charge and discharge.

Graphical abstract: Piperidinium tethered nanoparticle-hybrid electrolyte for lithium metal batteries

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Publication details

The article was received on 03 May 2014, accepted on 04 Jun 2014 and first published on 09 Jun 2014


Article type: Paper
DOI: 10.1039/C4TA02219J
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J. Mater. Chem. A, 2014,2, 11866-11873

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    Piperidinium tethered nanoparticle-hybrid electrolyte for lithium metal batteries

    K. S. Korf, Y. Lu, Y. Kambe and L. A. Archer, J. Mater. Chem. A, 2014, 2, 11866
    DOI: 10.1039/C4TA02219J

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