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Issue 7, 2014
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Rh(iii)-catalyzed C–H functionalization/aromatization cascade with 1,3-dienes: a redox-neutral and regioselective access to isoquinolines

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Abstract

An efficient rhodium(III)-catalyzed redox-neutral C–H activation/cyclization/isomerization strategy to prepare isoquinolines with complete regioselectivity from aromatic oxime esters and diverse 1,3-dienes is described. The advantages of this process are: (1) no need for an external oxidant; (2) simple and convenient reaction conditions; (3) complete regioselectivity; (4) broad scope of substrates.

Graphical abstract: Rh(iii)-catalyzed C–H functionalization/aromatization cascade with 1,3-dienes: a redox-neutral and regioselective access to isoquinolines

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Supplementary files

Article information


Submitted
27 Feb 2014
Accepted
27 Mar 2014
First published
28 Mar 2014

Chem. Sci., 2014,5, 2869-2873
Article type
Edge Article

Rh(III)-catalyzed C–H functionalization/aromatization cascade with 1,3-dienes: a redox-neutral and regioselective access to isoquinolines

D. Zhao, F. Lied and F. Glorius, Chem. Sci., 2014, 5, 2869 DOI: 10.1039/C4SC00628C

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