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Issue 71, 2015
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Dimeric resorcinarene salt capsules with very tight encapsulation of anions and guest molecules

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Abstract

Crystallization of N-cyclohexyl ammonium resorcinarene triflate from methanol results in a dimeric capsule capable of trapping two triflate anions and two methanol molecules within a 341 Å3 cavity while with 1,4-dioxane as a guest it forms a new larger dimeric capsule with volume of 679 Å3 encapsulating four 1,4-dioxane and four water molecules, resulting in packing coefficients of 0.75 and 0.67, respectively.

Graphical abstract: Dimeric resorcinarene salt capsules with very tight encapsulation of anions and guest molecules

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Article information


Submitted
20 May 2015
Accepted
25 Jun 2015
First published
25 Jun 2015

This article is Open Access

RSC Adv., 2015,5, 57912-57916
Article type
Communication
Author version available

Dimeric resorcinarene salt capsules with very tight encapsulation of anions and guest molecules

F. Pan, N. K. Beyeh and K. Rissanen, RSC Adv., 2015, 5, 57912
DOI: 10.1039/C5RA11905G

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