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Issue 71, 2015
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Dimeric resorcinarene salt capsules with very tight encapsulation of anions and guest molecules

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Abstract

Crystallization of N-cyclohexyl ammonium resorcinarene triflate from methanol results in a dimeric capsule capable of trapping two triflate anions and two methanol molecules within a 341 Å3 cavity while with 1,4-dioxane as a guest it forms a new larger dimeric capsule with volume of 679 Å3 encapsulating four 1,4-dioxane and four water molecules, resulting in packing coefficients of 0.75 and 0.67, respectively.

Graphical abstract: Dimeric resorcinarene salt capsules with very tight encapsulation of anions and guest molecules

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Publication details

The article was received on 20 May 2015, accepted on 25 Jun 2015 and first published on 25 Jun 2015


Article type: Communication
DOI: 10.1039/C5RA11905G
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Citation: RSC Adv., 2015,5, 57912-57916
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    Dimeric resorcinarene salt capsules with very tight encapsulation of anions and guest molecules

    F. Pan, N. K. Beyeh and K. Rissanen, RSC Adv., 2015, 5, 57912
    DOI: 10.1039/C5RA11905G

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