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Issue 107, 2014
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Highly luminescent imidoylamidinato platinum(ii) complexes formed by the coupling of 1H-pyrazole-1-carboxamidine with nitriles used as reaction solvents

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Abstract

A series of imidoylamidinato Pt(II) complexes have been prepared by the reaction of [Pt(bpy)(RCN)2]2+ (R = Me, Et, Ph) generated in a nitrile solution with 1H-pyrazole-1-carboxamidine. These complexes exhibit bright yellow or yellow-green luminescence in the solid state and mechanochromic behavior.

Graphical abstract: Highly luminescent imidoylamidinato platinum(ii) complexes formed by the coupling of 1H-pyrazole-1-carboxamidine with nitriles used as reaction solvents

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Publication details

The article was received on 03 Oct 2014, accepted on 11 Nov 2014 and first published on 18 Nov 2014


Article type: Communication
DOI: 10.1039/C4RA11744A
RSC Adv., 2014,4, 62186-62189

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    Highly luminescent imidoylamidinato platinum(II) complexes formed by the coupling of 1H-pyrazole-1-carboxamidine with nitriles used as reaction solvents

    T. Tanaka, R. Nouchi, Y. Nakao, Y. Arikawa and K. Umakoshi, RSC Adv., 2014, 4, 62186
    DOI: 10.1039/C4RA11744A

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