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Issue 10, 2014
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Palladium-catalyzed annulation of internal alkynes in aqueous medium

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Abstract

To facilitate precatalyst recovery and reuse, we have developed a fluorous, oxime-based palladacycle 1 and demonstrated that it is a very efficient and versatile precatalyst for carbo- and heteroannulation of internal alkynes with functionalized aryl halides in aqueous medium. A uniform reaction condition for these annulation reactions was also developed.

Graphical abstract: Palladium-catalyzed annulation of internal alkynes in aqueous medium

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Supplementary files

Article information


Submitted
22 Oct 2013
Accepted
02 Dec 2013
First published
02 Dec 2013

RSC Adv., 2014,4, 4921-4929
Article type
Paper

Palladium-catalyzed annulation of internal alkynes in aqueous medium

W. J. Ang, C. Tai, L. Lo and Y. Lam, RSC Adv., 2014, 4, 4921
DOI: 10.1039/C3RA46010J

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