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Issue 4, 2014
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Intermolecular bromoesterification of conjugated enynes: an efficient synthesis of bromoallenes

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Abstract

We have discovered that bromine electrophile and carboxylate nucleophile can be added to conjugated enynes intermolecularly in a 1,4-fashion with high diastereoselectivity. Highly functionalized bromoallenes with an adjacent stereogenic centre were prepared from readily available conjugated 1,3-enynes.

Graphical abstract: Intermolecular bromoesterification of conjugated enynes: an efficient synthesis of bromoallenes

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Publication details

The article was received on 31 Dec 2013, accepted on 08 Mar 2014 and first published on 20 Mar 2014


Article type: Research Article
DOI: 10.1039/C3QO00088E
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Org. Chem. Front., 2014,1, 386-390

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    Intermolecular bromoesterification of conjugated enynes: an efficient synthesis of bromoallenes

    H. Wang, W. Zhang, C. M. Schienebeck, S. R. Bennett and W. Tang, Org. Chem. Front., 2014, 1, 386
    DOI: 10.1039/C3QO00088E

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