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Issue 1, 2014
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Copper-catalyzed cross-coupling of bromozinc-difluoromethylphosphonate with iodo/bromo-aryl triazenes

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Abstract

A versatile method for the preparation of aryldifluoromethylphosphonates has been developed. This represents the first example of copper-catalyzed difluoroalkylation of ArBr and provides a useful and facile access to diverse aryldifluoromethylphosphonates that are difficult to prepare otherwise.

Graphical abstract: Copper-catalyzed cross-coupling of bromozinc-difluoromethylphosphonate with iodo/bromo-aryl triazenes

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Publication details

The article was received on 18 Nov 2013, accepted on 07 Dec 2013 and first published on 23 Dec 2013


Article type: Research Article
DOI: 10.1039/C3QO00044C
Org. Chem. Front., 2014,1, 113-116

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    Copper-catalyzed cross-coupling of bromozinc-difluoromethylphosphonate with iodo/bromo-aryl triazenes

    Z. Feng, Y. Xiao and X. Zhang, Org. Chem. Front., 2014, 1, 113
    DOI: 10.1039/C3QO00044C

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