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Issue 14, 2014
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Semimetallic molybdenum disulfide ultrathin nanosheets as an efficient electrocatalyst for hydrogen evolution

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Abstract

Molybdenum disulfide (MoS2) ultrathin nanosheets, as a well-known inorganic two dimensional (2D) material with a graphene-like structure, has attracted tremendous attention due to its unique microscopic and macroscopic properties brought by the confinement of charge and heat transfer upon the basal plane. However, as the prototype Mott-insulator, its relatively low conductivity and carrier concentration still greatly hamper its wide applications. Here, we developed a novel intralayer vanadium-doping strategy to produce semimetallic vanadium-doped MoS2 (VMS) ultrathin nanosheets with less than five S–(V, Mo)–S atomic layers, as a new inorganic 2D material. By incorporation of intralayer vanadium atoms, fine regulation of intrinsic electrical properties within the pristine MoS2 structure has been successfully realized, achieving semimetallic MoS2-based 2D materials with tunable conductivity and higher carrier concentration for the first time. Benefiting from the enhanced in-plane conductivity, the improved carrier concentration as well as the shortened electron transfer paths, the semimetal-like VMS nanosheet have enhanced catalytic activity with an overpotential of 0.13 V and a smaller Tafel slope, exhibiting enhanced catalytic performance compared with that of a pure MoS2 system. The intralayer doping in the 2D structure opens a new avenue in building highly efficient catalysts through the regulation of their intrinsic electrical properties, and also gives a new perspective for enlarging the design space of 2D materials.

Graphical abstract: Semimetallic molybdenum disulfide ultrathin nanosheets as an efficient electrocatalyst for hydrogen evolution

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Publication details

The article was received on 08 Apr 2014, accepted on 22 May 2014 and first published on 26 May 2014


Article type: Paper
DOI: 10.1039/C4NR01894J
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Nanoscale, 2014,6, 8359-8367

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    Semimetallic molybdenum disulfide ultrathin nanosheets as an efficient electrocatalyst for hydrogen evolution

    X. Sun, J. Dai, Y. Guo, C. Wu, F. Hu, J. Zhao, X. Zeng and Y. Xie, Nanoscale, 2014, 6, 8359
    DOI: 10.1039/C4NR01894J

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