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Issue 7, 2014
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Unprecedented non-cytotoxic [CoIII4LnIII]-core complexes with a tripodal oxime ligand – synthesis, structure, properties and potential applications

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Abstract

A series of [LnIII(H2O)2CoIII4O2Hx(Ox3H)4](ClO4)y (Ln = Gd (1), Sm (2), La (3); x = 0, 1; y = 3, 4) complexes (where Ox3H3 = tris(2-hydroxyiminopropyl)amine) with a novel-topology heterometallic core are presented. 1 is paramagnetic and 2 is weakly paramagnetic. The complexes were also characterized by IR spectroscopy, EDX, cyclic voltammetry, ESI-MS and elemental analyses. Potential for biological applications was assessed with MTT and stability tests.

Graphical abstract: Unprecedented non-cytotoxic [CoIII4LnIII]-core complexes with a tripodal oxime ligand – synthesis, structure, properties and potential applications

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Publication details

The article was received on 07 Feb 2014, accepted on 03 Apr 2014 and first published on 04 Apr 2014


Article type: Paper
DOI: 10.1039/C4NJ00194J
New J. Chem., 2014,38, 2894-2901

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    Unprecedented non-cytotoxic [CoIII4LnIII]-core complexes with a tripodal oxime ligand – synthesis, structure, properties and potential applications

    D. Premužić, S. Muche and M. Hołyńska, New J. Chem., 2014, 38, 2894
    DOI: 10.1039/C4NJ00194J

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