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Issue 6, 2014

Multigram synthesis of bis[(trimethylsilyl)ethynyl]benzenes suitable for post-polymerization modification

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Abstract

Novel substituted bis[(trimethylsilyl)ethynyl]benzenes have been prepared as versatile building blocks for organic functional materials. The resulting effects of replacing sulfur by selenium and tellurium on photophysical and electrochemical properties have been examined. Polymerization via microwave-assisted Cu(I)-catalyzed azide–alkyne cycloaddition (CuAAC) and subsequent post-polymerization modification by oxidation reveals the utility of the developed building blocks.

Graphical abstract: Multigram synthesis of bis[(trimethylsilyl)ethynyl]benzenes suitable for post-polymerization modification

Supplementary files

Article information


Submitted
02 Jan 2014
Accepted
03 Mar 2014
First published
04 Mar 2014

New J. Chem., 2014,38, 2229-2232
Article type
Letter
Author version available

Multigram synthesis of bis[(trimethylsilyl)ethynyl]benzenes suitable for post-polymerization modification

F. Glöcklhofer, D. Lumpi, B. Stöger and J. Fröhlich, New J. Chem., 2014, 38, 2229 DOI: 10.1039/C4NJ00011K

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