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Issue 11, 2018
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Buchwald–Hartwig amination using Pd(i) dimer precatalysts supported by biaryl phosphine ligands

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Abstract

We report the synthesis of air-stable Pd(I) dimer complexes featuring biaryl phosphine ligands. Catalytic experiments suggest that these complexes are competent precatalysts that can mediate cross-coupling amination reactions between aryl halides with both aliphatic and aromatic amine nucleophiles. This work represents an expansion of the air-stable precatalyst toolbox for Pd-catalyzed cross-coupling transformations.

Graphical abstract: Buchwald–Hartwig amination using Pd(i) dimer precatalysts supported by biaryl phosphine ligands

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Article information


Submitted
10 Jan 2018
Accepted
09 Feb 2018
First published
12 Feb 2018

Dalton Trans., 2018,47, 3684-3688
Article type
Communication

Buchwald–Hartwig amination using Pd(I) dimer precatalysts supported by biaryl phosphine ligands

K. O. Kirlikovali, E. Cho, T. J. Downard, L. Grigoryan, Z. Han, S. Hong, D. Jung, J. C. Quintana, V. Reynoso, S. Ro, Y. Shen, K. Swartz, E. Ter Sahakyan, A. I. Wixtrom, B. Yoshida, A. L. Rheingold and A. M. Spokoyny, Dalton Trans., 2018, 47, 3684
DOI: 10.1039/C8DT00119G

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