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Issue 7, 2017
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Isolation of an unusual [Cu6] nanocluster through sequential addition of copper(i) to a polynucleating ligand

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Abstract

Addition of 2 equiv. of CuI to a [Cu]4 multimetallic complex results in cluster formation leading to the isolation of a rare bicapped tetrahedral [Cu6I2] cluster that is stabilised by two conformationally constrained polynucleating ligands.

Graphical abstract: Isolation of an unusual [Cu6] nanocluster through sequential addition of copper(i) to a polynucleating ligand

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Article information


Submitted
07 Nov 2016
Accepted
20 Jan 2017
First published
20 Jan 2017

Dalton Trans., 2017,46, 2077-2080
Article type
Communication

Isolation of an unusual [Cu6] nanocluster through sequential addition of copper(I) to a polynucleating ligand

A. Phanopoulos, M. Warren, A. J. P. White, A. Horton and M. R. Crimmin, Dalton Trans., 2017, 46, 2077
DOI: 10.1039/C6DT04703C

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