Structural modulation in two CuII-based MOFs by synergistic assembly involving the mixed-ligand synthetic strategy and the solvent effect

Yun-Wu Li; Da-Cheng Li; Jian Xu; Hong-Guo Hao; Su-Na Wang; Jian-Min Dou; Tong-Liang Hu; Xian-He Bu

doi:10.1039/C4DT02321H

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Structural modulation in two Cu^II-based MOFs by synergistic assembly involving the mixed-ligand synthetic strategy and the solvent effect†

Yun-Wu Li,^ab Da-Cheng Li,^a Jian Xu,^b Hong-Guo Hao,^a Su-Na Wang,^a Jian-Min Dou,*^a Tong-Liang Hu*^b and Xian-He Bu^b

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* Corresponding authors

^a School of Chemistry and Chemical Engineering, and Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, P. R. China
E-mail: dougroup@163.com

^b Department of Chemistry, TKL of Metal- and Molecule-Based Material Chemistry, and Synergetic Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, P. R. China
E-mail: tlhu@nankai.edu.cn

Abstract

Two Cu^II-based MOFs have been constructed by synergistic assembly involving the mixed-ligand synthetic strategy and the solvent effect. Compound 1 is a 3D structure and represents a cds topology, while compound 2 displays a rare structure built by three distinct {Cu₄} clusters as SBUs. Moreover, the magnetic properties of 2 have been thoroughly investigated.

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Article information

DOI: https://doi.org/10.1039/C4DT02321H
Article type: Communication
Submitted: 31 Jul 2014
Accepted: 04 Sep 2014
First published: 04 Sep 2014

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Dalton Trans., 2014,43, 15708-15712

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Structural modulation in two Cu^II-based MOFs by synergistic assembly involving the mixed-ligand synthetic strategy and the solvent effect

Y. Li, D. Li, J. Xu, H. Hao, S. Wang, J. Dou, T. Hu and X. Bu, Dalton Trans., 2014, 43, 15708 DOI: 10.1039/C4DT02321H

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