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Issue 43, 2014
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Unusual assembly of lacunary heteropolymolybdates with cyanometalate fragment

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Abstract

Two new cyanide-bridged heteropolymolybdate complexes have been synthesized by a facile self-assembly process in aqueous solution, which demonstrates a successful tactic to incorporate the cyanometalate fragment into lacunary heteropolymolybdate. Magnetic investigation showed that complex 2 exhibits slow magnetic relaxation behavior.

Graphical abstract: Unusual assembly of lacunary heteropolymolybdates with cyanometalate fragment

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Publication details

The article was received on 23 Jun 2014, accepted on 30 Jul 2014 and first published on 31 Jul 2014


Article type: Communication
DOI: 10.1039/C4DT01875C
Dalton Trans., 2014,43, 16147-16151

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    Unusual assembly of lacunary heteropolymolybdates with cyanometalate fragment

    Y. Wang, N. Jiang, F. Li, Y. Zheng, L. Xu and M. Sun, Dalton Trans., 2014, 43, 16147
    DOI: 10.1039/C4DT01875C

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