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Issue 43, 2014
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Low temperature activation of S8, Sered and α-Te with [CpBIGFe(CO)2] radicals

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Abstract

The bulky dimeric iron complex, [CpBIGFe(CO)2]2, readily activates elemental chalcogens (S8, Sered and α-Te) under mild conditions at room temperature. Six compounds containing Q22− ligands (Q = S, Se) and a Te2− ligand, respectively, were isolated and completely characterized, including by X-ray diffraction techniques.

Graphical abstract: Low temperature activation of S8, Sered and α-Te with [CpBIGFe(CO)2] radicals

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Publication details

The article was received on 14 Jun 2014, accepted on 22 Jul 2014 and first published on 22 Jul 2014


Article type: Communication
DOI: 10.1039/C4DT01764A
Dalton Trans., 2014,43, 16139-16142

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    Low temperature activation of S8, Sered and α-Te with [CpBIGFe(CO)2] radicals

    S. Heinl and M. Scheer, Dalton Trans., 2014, 43, 16139
    DOI: 10.1039/C4DT01764A

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