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Issue 28, 2014
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A truncated [MnIII12] tetrahedron from oxime-based [MnIII3O] building blocks

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Abstract

The use of the novel pro-ligand H4L combining the complimentary phenolic oxime and diethanolamine moieties in one organic framework, results in the formation of the first example of a [MnIII12] truncated tetrahedron and an extremely rare example of a Mn cage conforming to an Archimedean solid.

Graphical abstract: A truncated [MnIII12] tetrahedron from oxime-based [MnIII3O] building blocks

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Article information


Submitted
07 Feb 2014
Accepted
22 May 2014
First published
22 May 2014

Dalton Trans., 2014,43, 10690-10694
Article type
Communication
Author version available

A truncated [MnIII12] tetrahedron from oxime-based [MnIII3O] building blocks

J. M. Frost, S. Sanz, T. Rajeshkumar, M. B. Pitak, S. J. Coles, G. Rajaraman, W. Wernsdorfer, J. Schnack, P. J. Lusby and E. K. Brechin, Dalton Trans., 2014, 43, 10690
DOI: 10.1039/C4DT01469C

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