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Issue 32, 2014
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Chemical tuning of the magnetic relaxation in dysprosium(iii) mononuclear complexes

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Abstract

A dysprosium(III) complex, exhibiting slow relaxation of magnetization, was prepared. Crystallographic studies showed a perturbation of local symmetry upon deprotonation of the ligand, with concomitant faster relaxation of magnetization. This was attributed to a large shift in the direction of the main magnetic axis, as indicated by ab initio calculations.

Graphical abstract: Chemical tuning of the magnetic relaxation in dysprosium(iii) mononuclear complexes

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Supplementary files

Article information


Submitted
21 Mar 2014
Accepted
01 May 2014
First published
02 May 2014

Dalton Trans., 2014,43, 12146-12149
Article type
Communication
Author version available

Chemical tuning of the magnetic relaxation in dysprosium(III) mononuclear complexes

L. J. Batchelor, I. Cimatti, R. Guillot, F. Tuna, W. Wernsdorfer, L. Ungur, L. F. Chibotaru, V. E. Campbell and T. Mallah, Dalton Trans., 2014, 43, 12146
DOI: 10.1039/C4DT00846D

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