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Issue 5, 2014
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Synthesis and characterization of 1D iron(ii) spin crossover coordination polymers with hysteresis

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Abstract

Purposeful ligand design was used for the synthesis of eight new 1D iron(II) spin crossover coordination polymers aiming for cooperative spin transitions with hysteresis. The results from magnetic measurements and X-ray structure analysis show that the combination of rigid linkers and a hydrogen bond network between the 1D chains is a promising tool to reach this goal. Five of the eight new samples show a cooperative spin transition with hysteresis with up to 43 K wide hysteresis loops.

Graphical abstract: Synthesis and characterization of 1D iron(ii) spin crossover coordination polymers with hysteresis

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Publication details

The article was received on 23 Sep 2013, accepted on 08 Nov 2013 and first published on 12 Nov 2013


Article type: Paper
DOI: 10.1039/C3DT52635F
Dalton Trans., 2014,43, 1990-1999

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    Synthesis and characterization of 1D iron(II) spin crossover coordination polymers with hysteresis

    W. Bauer, C. Lochenie and B. Weber, Dalton Trans., 2014, 43, 1990
    DOI: 10.1039/C3DT52635F

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