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Issue 16, 2014
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High valence 3p and transition metal based MOFs

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Abstract

This article focuses on high valence 3p and transition metal based metal organic frameworks. In the first part we will discuss the complex solution chemistry of these metals which makes this sub-class of MOFs more of a challenge than the traditional low valence metal based MOFs. This is followed by a short review of the different classes of solids based on phosphonates, carboxylates and other linkers. Finally, we report some of the most relevant properties of these solids such as their chemical or thermal stability as well as their catalytic, redox- and photo-activities.

Graphical abstract: High valence 3p and transition metal based MOFs

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Publication details

The article was received on 20 Feb 2014 and first published on 20 Jun 2014


Article type: Review Article
DOI: 10.1039/C4CS00081A
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Chem. Soc. Rev., 2014,43, 6097-6115

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    High valence 3p and transition metal based MOFs

    T. Devic and C. Serre, Chem. Soc. Rev., 2014, 43, 6097
    DOI: 10.1039/C4CS00081A

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