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Issue 43, 2014
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Understanding the adsorption mechanism of noble gases Kr and Xe in CPO-27-Ni, CPO-27-Mg, and ZIF-8

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Abstract

An experimental study of Xe and Kr adsorption in metal–organic frameworks CPO-27-Ni, CPO-27-Mg, and ZIF-8 was carried out. In situ synchrotron X-ray powder diffraction experiments allowed precise determination of the adsorption sites and sequence of their filling with increasing of gas pressure at different temperatures. Structural investigations were used for interpretation of gas adsorption measurements.

Graphical abstract: Understanding the adsorption mechanism of noble gases Kr and Xe in CPO-27-Ni, CPO-27-Mg, and ZIF-8

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Article information


Submitted
24 Jul 2014
Accepted
16 Sep 2014
First published
17 Sep 2014

Phys. Chem. Chem. Phys., 2014,16, 23908-23914
Article type
Paper

Understanding the adsorption mechanism of noble gases Kr and Xe in CPO-27-Ni, CPO-27-Mg, and ZIF-8

O. V. Magdysyuk, F. Adams, H.-P. Liermann, I. Spanopoulos, P. N. Trikalitis, M. Hirscher, R. E. Morris, M. J. Duncan, L. J. McCormick and R. E. Dinnebier, Phys. Chem. Chem. Phys., 2014, 16, 23908
DOI: 10.1039/C4CP03298E

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