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Issue 29, 2014
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Synthesis of polycyclic substituted vinylarenes via a one-pot intramolecular aryl alkylation–N-tosylhydrazone insertion reaction

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Abstract

A novel method of a palladium-catalyzed/norbornene-mediated intramolecular C–H activation/N-tosylhydrazones insertion reaction is developed. In this process, various bicyclic or tricyclic substituted vinylarenes are obtained with high efficiency under mild conditions.

Graphical abstract: Synthesis of polycyclic substituted vinylarenes via a one-pot intramolecular aryl alkylation–N-tosylhydrazone insertion reaction

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Publication details

The article was received on 30 Jan 2014, accepted on 14 Feb 2014 and first published on 14 Feb 2014


Article type: Communication
DOI: 10.1039/C4CC00809J
Chem. Commun., 2014,50, 3882-3884

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    Synthesis of polycyclic substituted vinylarenes via a one-pot intramolecular aryl alkylation–N-tosylhydrazone insertion reaction

    X. Wu, P. Zhou, L. Wang, P. Xu and Y. Liang, Chem. Commun., 2014, 50, 3882
    DOI: 10.1039/C4CC00809J

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