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Issue 32, 2014
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Thiadiazole dioxide-fused picene: acceptor ability, anion radical formation, and n-type charge transport characteristics

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Abstract

Picene, which is an organic p-channel semiconductor and a component of superconductors, was derivatized with a thiadiazole-dioxide moiety to afford a novel acceptor molecule (PTDAO2). PTDAO2 can form stable anion radical species in solution and as a crystal, and its neutral crystalline thin film exhibits n-type transistor characteristics.

Graphical abstract: Thiadiazole dioxide-fused picene: acceptor ability, anion radical formation, and n-type charge transport characteristics

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Article information


Submitted
15 Dec 2013
Accepted
23 Jan 2014
First published
27 Jan 2014

Chem. Commun., 2014,50, 4178-4180
Article type
Communication

Thiadiazole dioxide-fused picene: acceptor ability, anion radical formation, and n-type charge transport characteristics

Y. Xie, Y. Shuku, M. M. Matsushita and K. Awaga, Chem. Commun., 2014, 50, 4178
DOI: 10.1039/C3CC49500K

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