Two dominant self-assembly pathways to a Pd3L6 double-walled triangle

Tomoki Tateishi; Shumpei Kai; Yuya Sasaki; Tatsuo Kojima; Satoshi Takahashi; Shuichi Hiraoka

doi:10.1039/C8CC02608D

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Two dominant self-assembly pathways to a Pd₃L₆ double-walled triangle†

Tomoki Tateishi,

^a Shumpei Kai,^a Yuya Sasaki,^a Tatsuo Kojima,

^a Satoshi Takahashi

^a and Shuichi Hiraoka

*^a

Author affiliations

* Corresponding authors

^a Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo, 3-8-1 Komaba, Meguro-ku, Tokyo 153-8902, Japan
E-mail: chiraoka@mail.ecc.u-tokyo.ac.jp

Abstract

An NMR-based quantitative analysis of self-assembly process (QASAP) for the self-assembly of a Pd₃L₆ double-walled triangle (DWT) from PdPy*₄(BF₄)₂ (Py* indicates 3-chloropyridine) and V-shaped ditopic ligands (L) revealed that DWT was assembled through trinuclear single-walled chains, in which the intramolecular macrocyclization and the formation of double-walls took place leading to the final assembly.

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Article information

DOI: https://doi.org/10.1039/C8CC02608D
Article type: Communication
Submitted: 31 Mar 2018
Accepted: 09 May 2018
First published: 10 May 2018

Download Citation

Chem. Commun., 2018,54, 7758-7761

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Two dominant self-assembly pathways to a Pd₃L₆ double-walled triangle

T. Tateishi, S. Kai, Y. Sasaki, T. Kojima, S. Takahashi and S. Hiraoka, Chem. Commun., 2018, 54, 7758 DOI: 10.1039/C8CC02608D

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Chemical Communications