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Issue 25, 2015
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Assessing dimerisation degree and cooperativity in a biomimetic small-molecule model by pulsed EPR

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Abstract

Pulsed electron paramagnetic resonance (EPR) spectroscopy is gaining increasing importance as a complementary biophysical technique in structural biology. Here, we describe the synthesis, optimisation, and EPR titration studies of a spin-labelled terpyridine Zn(II) complex serving as a small-molecule model system for tuneable dimerisation.

Graphical abstract: Assessing dimerisation degree and cooperativity in a biomimetic small-molecule model by pulsed EPR

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Submitted
31 Oct 2014
Accepted
08 Jan 2015
First published
08 Jan 2015

This article is Open Access

Chem. Commun., 2015,51, 5257-5260
Article type
Communication
Author version available

Assessing dimerisation degree and cooperativity in a biomimetic small-molecule model by pulsed EPR

K. Ackermann, A. Giannoulis, D. B. Cordes, A. M. Z. Slawin and B. E. Bode, Chem. Commun., 2015, 51, 5257
DOI: 10.1039/C4CC08656B

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